In 2017-18, his side reached the quarters and won the first leg of the tie by a 4-1 margin.
However, Roma staged an incredible fight to progress after sealing the second leg 3-0.
A similar story unfolded last season.
Barcelona beat Liverpool in the first leg and were stunned at Anfield next.
Barcelona lead the proceedings in La Liga 2019-20
In the ongoing 2019-20 season, Valverde managed 19 games in La Liga and Barcelona lead the proceedings and are ahead of Real on goal-difference. His side amassed 49 goals to once again register the best numbers so far.
Valverde had a win percentage of 66.90
Valverde managed Barca in 145 matches across competitions. His side won a staggering 97 matches, drew 32 and lost just 16. He enjoyed a win percentage of 66.90. In La Liga itself, Valverde won a staggering 66 games in charge of the club since 2017-18.